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The vibrational temperature

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  • Temperature — This article is about the thermodynamic property. For other uses, see Temperature (disambiguation). A map of global long term monthly average surface air temperatures i …   Wikipedia

  • Glass transition temperature — The glass transition temperature, T g, is the temperature at which an amorphous solid, such as glass or a polymer, becomes brittle on cooling, or soft on heating. More specifically, it defines a pseudo second order phase transition in which a… …   Wikipedia

  • Basic physics of the violin — The distinctive sound of a violin is the result of interactions between its many parts. Drawing a bow across the strings causes them to vibrate. This vibration is transmitted through the bridge and sound post to the body of the violin (mainly the …   Wikipedia

  • Rotational temperature — The rotational temperature is commonly used in thermodynamics, to simplify certain equations. It has units of temperature and is defined as heta {rot} = frac{ar B}{k}Where ar B is the rotational constant, and k is the Boltzmann constant, given… …   Wikipedia

  • Thermodynamic temperature — is the absolute measure of temperature and is one of the principal parameters of thermodynamics. Thermodynamic temperature is an “absolute” scale because it is the measure of the fundamental property underlying temperature: its null or zero point …   Wikipedia

  • Negative temperature — In physics, certain systems can achieve negative temperatures; that is, their thermodynamic temperature can be a negative quantity. Negative temperatures can be expressed as negative numbers on the kelvin scale. Temperatures that are expressed as …   Wikipedia

  • Kinetic isotope effect — The kinetic isotope effect (KIE) is the ratio of reaction rates of two different isotopically labeled molecules in a chemical reaction. It is also called isotope fractionation, although this term is somewhat broader in meaning. A KIE involving… …   Wikipedia

  • Greenhouse effect — The Greenhouse effect refers to the change in the thermal equilibrium temperature of a planet or moon by the presence of an atmosphere containing gas that absorbs infrared radiation. [ [http://www.ipcc.ch/pdf/assessment report/ar4/syr/ar4 syr… …   Wikipedia

  • Franck-Condon principle — The Franck Condon principle is a rule in spectroscopy and quantum chemistry that explains the intensity of vibronic transitions. Vibronic transitions are the simultaneous changes in electronic and vibrational energy levels of a molecule due to… …   Wikipedia

  • Zero-phonon line and phonon sideband — The zero phonon line and the phonon sideband jointly constitute the line shape of individual light absorbing and emitting molecules (chromophores) embedded into a transparent solid matrix. When the host matrix contains many chromophores, each… …   Wikipedia

  • Heat capacity ratio — The heat capacity ratio or adiabatic index or ratio of specific heats, is the ratio of the heat capacity at constant pressure (C P) to heat capacity at constant volume (C V). It is sometimes also known as the isentropic expansion factor and is… …   Wikipedia

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